New insights into the origin and migration of brines in deep Devonian aquifers, Alberta, Canada     

Karsten Michael  Hans G. Machel  Stefan Bachu 《Journal of Geochemical Exploration》2003,80(2-3):193-219

Analysis of hydraulic heads and chemical compositions of Devonian formation waters in the west central part of the Alberta Basin, Canada, characterizes the origin of formation waters and migration of brines. The Devonian succession in the study area lies 2000–5000 m below the ground surface, and has an approximate total thickness of 1000 m and an average slope of 15 m/km. Four Devonian aquifers are present in the study area, which form two aquifer systems [i.e., a Middle–Upper Devonian aquifer system (MUDAS) consisting of the Elk Point and Woodbend–Beaverhill Lake aquifers, and an Upper Devonian aquifer system (UDAS) consisting of the Winterburn and Wabamun aquifers]. The Ireton is an effective aquitard between these two systems in the eastern parts of the study area. The entire Devonian succession is confined below by efficient aquitards of the underlying Cambrian shales and/or the Precambrian basement, and above by overlying Carboniferous shales of the Exshaw and Lower Banff Formations.The formation water chemistry shows that the Devonian succession contains two distinct brine types: a ‘heavy brine,’ located updip, defined approximately by TDS >200 g/l, and a ‘light brine’ with TDS <200 g/l. Hydraulic head distributions suggest that, presently, the ‘light brine’ attempts to flow updip, thereby pushing the ‘heavy brine’ ahead. The interface between the two brines is lobate and forms large-scale tongues that are due to channeled flow along high-permeability pathways. Geological and hydrogeochemical data suggest that the following processes determined the present composition of the ‘light’ and ‘heavy’ brines: original seawater, evaporation beyond gypsum but below halite saturation, dolomitization, clay dehydration, gypsum dewatering, thermochemical sulfate reduction (TSR), and halite dissolution. The influx of meteoric (from the south) and metamorphic (from the west) waters can be recognized only in the ‘light brine.’ Albitization can be unequivocally identified only in the ‘heavy brine.’ The ‘heavy brine’ may be residual Middle Devonian evaporitic brine from the Williston Basin or the Elk Point Basin, or it may have originated from partial dissolution of thick, laterally extensive Middle Devonian evaporite deposits to the east of the study area. The ‘light brine’ most probably originated from dilution of ‘heavy brine’ in post-Laramide times.  相似文献   

Testing theories of the vertical stratification of the ACC against observations     

Richard H. Karsten  John Marshall   《Dynamics of Atmospheres and Oceans》2002,36(1-3)

Recent theories of the Antarctic Circumpolar Current (ACC) suggest that its lateral and vertical stratification is controlled by its baroclinic instability: eddies in the ACC not only feed-off the available potential energy stored in sloping isopycnals but play a central role is setting up that stratification. Simple theory makes predictions about how the depth of the thermocline in the ACC depends on the surface winds, the air–sea buoyancy flux and transfer by baroclinic eddies. By examining gridded hydrographic data, here we test some of these predictions against observations. We show that, to a remarkable degree, the buoyancy field in the ACC decays exponentially with depth beneath the mixed layer. The e-folding depth increases equatorward, from less than 500 m on the poleward flank of the ACC to greater then 1000 m on its equatorial flank, in a manner that is broadly consistent with the theory.  相似文献   

Dissolved inorganic nutrients and organic substrates in the River Warnow (North-Eastern Germany) – Utilisation by bacterioplankton     

Heike M. Freese  Solvig Grs  Ulf Karsten  Rhena Schumann 《Limnologica》2007,37(3):264-277

After 1990, external loads of Central European rivers with inorganic nutrients (nitrogen and phosphorus) and organic material were reduced because of changed environmental laws. However, in the eutrophic lowland River Warnow, North-Eastern Germany, nitrate concentrations remained high with 35–185 μmol l⁻¹ without a significant decrease since 1992. In contrast, phosphate concentrations, varying between 0.3 and 5.2 μmol l⁻¹ during the growth season 2002, decreased significantly over the years. However, its concentrations still exceeded 1 μmol l⁻¹ regularly in the growth seasons. This load led to a substantial accumulation of organic matter additional to high terrestrial inputs. Despite the high organic load, the remineralising bacteria were mainly inactive in River Warnow. Therefore, the composition of the dissolved organic material, especially its bioavailability, were investigated during the growth season 2002 and discussed with other potential controlling factors. River Warnow carried a high load of dissolved organic carbon (14 mg l⁻¹), especially of humic substances (5.5 mg C l⁻¹). Bacterial abundance (12×10⁶ ml⁻¹) as well as production (1.7 μg C l⁻¹ h⁻¹) depended on temperature. During late spring and summer at constantly higher temperatures, bacterial production correlated positively to readily utilisable substrates and to humic compounds. Thus, the bacterial community in River Warnow may be well adapted or contain enough species using the available amino acids and carbohydrates as well as humic matter compounds. However, calculated from protozoan biomass, grazing may control bacterial biomass and perhaps community composition profoundly, what lead to the low percentages of active bacteria.  相似文献   

Evolution of a calcite marble shear zone complex on Thassos Island, Greece: microstructural and textural fabrics and their kinematic significance   总被引：1，自引：0，他引：1  

Michel Bestmann  Karsten Kunze  Alan Matthews 《Journal of Structural Geology》2000,22(11-12)

The deformation history of a monophase calcite marble shear zone complex on Thassos Island, Northern Greece, is reconstructed by detailed geometric studies of the textural and microstructural patterns relative to a fixed reference system (shear zone boundary, SZB). Strain localization within the massive marble complex is linked to decreasing P–T conditions during the exhumation process of the metamorphic core complex. Solvus thermometry indicates that temperatures of 300–350°C prevailed during part of the shear zone deformation history. The coarse-grained marble protolith outside the shear zone is characterized by symmetrically oriented twin sets due to early coaxial deformation. A component of heterogeneous non-coaxial deformation is first recorded within the adjacent protomylonite. Enhanced strain weakening by dynamic recrystallization promoted strong localization of plastic deformation in the ultramylonite of the calcite shear zone, where high strain was accommodated by non-coaxial flow. This study demonstrates that both a pure shear and a simple shear strain path can result in similar crystallographic preferred orientations (single c-axis maximum perpendicular to the SZB) by different dominant deformation mechanisms. Separated a-axis pole figures (+a- and −a-axis) show different density distributions with orthorhombic texture symmetry in the protolith marble and monoclinic symmetry in the ultramylonite marble consistently with the observed grain fabric symmetry.  相似文献   

Hydrological modelling in the anthroposphere: predicting local runoff in a heavily modified high-alpine catchment     

Johannes Wesemann  Mathew Herrnegger  Karsten Schulz 《山地科学学报》2018,15(5):921-938

Hydrological models within inflow forecasting systems for high-alpine hydropower reservoirs can provide valuable information as part of a decision support system for the improvement of hydropower production or flood retention. The information, especially concerning runoff, is however rarely available for the calibration of the hydrological models used. Therefore, a method is presented to derive local runoff from secondary information for the calibration of the model parameters of the rainfallrunoff model COSERO. Changes in water levels in reservoirs, reservoir outflows, discharge measurements at water intakes and in transport lines are thereby used to derive the local, “natural” flow for a given sub-catchment. The proposed method is applied within a research study for the ÖBB Infrastructure Railsystem division in the Stubache catchment in the central Austrian Alps. Here, the ÖBB operates the hydropower scheme “Kraftwerksgruppe Stubachtal”, which consists of 7 reservoirs and 4 hydropower stations. The hydrological model has been set up considering this human influences and the high natural heterogeneity in topography and land cover, including glaciers. Overall, the hydrological model performs mostly well for the catchment with highest NSE values of 0.78 for the calibration and 0.79 for the validation period, also considering the use of homogeneous parameter fields and the uncertainty of the derived local discharge values. The derived runoff data proved to be useful information for the model calibration. Further analysis, examining the water balance and its components as well as snow cover, showed satisfactory simulation results. In conclusion, a unique runoff dataset for a small scale high-alpine catchment has been created to establish a hydrological flow prediction model which in a further step can be used for improved and sustainable hydropower management.  相似文献   

Rates of trace metal and nutrient diagenesis in an intertidal creek bank     

Thomas Riedel  Karsten Lettmann  Melanie Beck 《Geochimica et cosmochimica acta》2011,75(1):134-6555

Carbon mineralization in marine sediments is a key process involved in the cycling of carbon, nutrients and trace metals. However, as marine sediments are usually diffusion dominated, the pace of element and nutrient cycling is slow, because consumption of oxidants and/or nutrients in the pore waters via microbial activity often outpaces resupply. Adding an advective flow component to such a system should change the biogeochemical dynamics considerably. Numerical simulations show that shallow coastal aquifers affected by tidal forces can establish ground water velocities of up to 7 cm h⁻¹, driving a circulation of sea water through the sediments with subsequent discharge. Although known to enhance solute exchange, the impact of advection on early diagenesis has not received much attention.To address this issue we mapped the interstitial water chemistry down to 2.5 m sediment depth along a transect on an intertidal creek bank that is subject to a periodic advective flow. Additionally a recently developed hydrogeological simulation of the creek bank was applied to calculate ages of the sampled pore waters. Sample ages obtained were used to quantify (flow path integrated) production or depletion rates for trace metals, nutrients, and sulphate.We find young sea water percolating relatively fast through sediments close to the creek showing strong signs of alteration, whereas pore waters from diffusion dominated regions are less altered. The increase in inorganic nutrients and some trace elements along the flow path requires high rates of turnover. Sulphate, molybdenum, and uranium are almost completely depleted after 200 days, while dissolved inorganic carbon (DIC), ammonia, and manganese increase. Averaged production rates for DIC appear to be three times higher when advection dominated the subsurface flow regime. Our results demonstrate that sites dominated by advection generally show signs of faster rates of diagenetic reactions.  相似文献   

Ecological stability during the LGM and the mid-Holocene in the Alpine Steppes of Tibet?     

Georg Miehe  Sabine Miehe  Kerstin Bach  Jürgen Kluge  Karsten Wesche  Yang Yongping  Liu Jianquan 《Quaternary Research》2011,76(2):243-252

Arid and Alpine ecosystems are known for extreme environmental changes during the Late Quaternary. We hypothesize that the world's largest Alpine arid ecosystem however, the Alpine Steppes of the Tibetan highlands, remained ecologically stable during the LGM and the mid-Holocene. This hypothesis is tested by distributional range of plant species, plant life forms and rate of endemism. The set of character species has a precipitation gradient between 50 and 350 mm/a, testifying for resilience to precipitation changes. 83% of the species have a wider vertical range than 1000 m used as a proxy for resilience to temperature changes. 30% of the species are endemic with 10 endemic genera, including plate-shaped cushions as a unique plant life form. These findings are in line with palaeo-ecological proxies (δ¹⁸O, pollen) allowing the assumption that Alpine Steppes persisted during the LGM with 3 to 4 K lower summer temperatures.During the mid-Holocene, forests could have replaced Alpine Steppes in the upper catchments of the Huang He, Yangtze, Mekong, Salween and Yarlung Zhangbo, but not in the interior basins of the north-western highlands, because the basins were then flooded, suppressing forests and supporting the environmental stability of this arid Alpine grassland biome.  相似文献   

A case study on the correlation of micro-contaminants and potassium in the Leine River (Germany)   总被引：1，自引：0，他引：1  

Karsten Nödler  Tobias Licha  Steffi Fischer  Bianca Wagner  Martin Sauter 《Applied Geochemistry》2011,26(12):2172-2180

River monitoring with focus on the correlation of 41 micro-contaminants with K⁺ and its temporal and spatial variation was carried out in the Leine River (Germany). A positive correlation of concentrations of wastewater-related micro-contaminants and K⁺ is to be expected in receiving waters of wastewater treatment plant (WWTP) effluent since urine is a significant source of K⁺ in WWTP effluent. This correlation was found for compounds, which meet the following criteria: (1) WWTP effluent is the dominating source of the compound, (2) variability of its mass flux in the WWTP is negligible, and (3) the compound is persistent in WWTPs and in the environment. The excellent positive correlation of carbamazepine with K⁺ resulted in the fitting of a universal linear equation to the summer and winter data. For almost all other correlating compounds (1H-benzotriazole, citalopram, diclofenac, metoprolol, sotalol, sulfamethoxazole and tolyltriazole), slopes of the line fittings were steeper in winter (x-axis: K⁺, y-axis: respective micro-contaminant). This has been attributed to a presumed lower degree of degradation and attenuation within WWTPs and in the environment due to low temperatures as well as an increase in consumption of these compounds in the winter months. As part of this research, a sampling event along the entire flow path of the Leine River (∼280 km) was conducted to identify compounds demonstrating stable ratios of various respective micro-contaminants with K⁺. Among other compounds, carbamazepine, sulfamethoxazole, and tolyltriazole demonstrated the best correlations with R² > 0.89. Potassium-equivalents of the individual micro-contaminants depended on land use and population structure of the investigated river section.  相似文献   

On the role of domain size and resolution in the simulations with the HIRHAM region climate model     

Morten A. D. Larsen  Peter Thejll  Jens H. Christensen  Jens C. Refsgaard  Karsten H. Jensen 《Climate Dynamics》2013,40(11-12):2903-2918

We investigate the simulated temperature and precipitation of the HIRHAM regional climate model using systematic variations in domain size, resolution and detailed location in a total of eight simulations. HIRHAM was forced by ERA-Interim boundary data and the simulations focused on higher resolutions in the range of 5.5–12 km. HIRHAM outputs of seasonal precipitation and temperature were assessed by calculating distributed model errors against a higher resolution data set covering Denmark and a 0.25° resolution data set covering Europe. Furthermore the simulations were statistically tested against the Danish data set using bootstrap statistics. The results from the distributed validation of precipitation showed lower errors for the winter (DJF) season compared to the spring (MAM), fall (SON) and, in particular, summer (JJA) seasons for both validation data sets. For temperature, the pattern was in the opposite direction, with the lowest errors occurring for the JJA season. These seasonal patterns between precipitation and temperature are seen in the bootstrap analysis. It also showed that using a 4,000 × 2,800 km simulation with an 11 km resolution produced the highest significance levels. Also, the temperature errors were more highly significant than precipitation. In similarly sized domains, 12 of 16 combinations of variables, observation validation data and seasons showed better results for the highest resolution domain, but generally the most significant improvements were seen when varying the domain size.  相似文献   

Preliminary Mapping and Characterisation of Soils in the Pirin Mountains （Bulgaria）     

Maika LaeBiger  ;Joerg Scheithauer  ;Karsten Grunewald 《山地科学学报》2008,5(2):122-129

Soil types, humus types and vegetation as well as their hypsometric variation were analysed in terms of sequences in the northern part of the high mountains of the Pirin National Park at altitudes between looo and 2400 m a.s.1. The study area is characterised by a large variety of natural parameters like petrology （mainly marble and granite）, morphology （different slope deposits, exposition） and the orographic climate gradient. Statistical analyses using these parameters provided a basis for the soil group classification of the sites. Based on a Digital Terrain Model （DTM） and a geological map of the Pirin National Park, the results of these statistical analyses were used to generate a ＂map of potential soil groups＂ （regionalisation using GIS）. Six potential soil groups could be determined. The resulting map exhibits a confidence level of 68 % on 74.4 % of the covered area. Rendzic Leptosols, in combination with Folic Histosols and Histi-lithic Leptosols occur in the alpine and subalpine regions on calcareous substrates. With decreasing altitude they are replaced by a mosaic of Rendzic Leptosols, Phaeozems and an increasing occurrence of Cambic Umbrisols. Umbrisols found on silicatic substrates in the alpine region are replaced by Cambic Umbrisols with decreasing altitude as well. Hence, pedogenesis is characterised by increasing browning and depth of the soil profiles with decreasing altitude. The pH-level is slightly acidic to neutral in lower zones and on calcareous rocky bases. Acidification increases in the subalpine zone. Soil pH decreases down to 4 on silicate subtrates. Typical humic values in mineral topsoils are 10 to 12 %, and in organic layers of the soils above 2000 m a.s.1, they are even more. The C：N ratio closely ranges around 20 （median）.  相似文献